DOI: 10.15330/pcss.16.1.202-206

A.I. Nesterenko, N.G. Nesterenko

Pushing of Interstitial Elements in the Transition Zone under the Growing Diffusion Layers

Ukrainian State University of Chemical Technology (Gagarin Avenue, 8, Dnepropetrovsk 49005; e-mail:ngn1950@ukr.net)

The kinetics of diffusion of interstitial elements on the example of diffusion saturation with boron and silicon iron- carbon matrix ( - iron) was considered . The layers of intermetallic Fe - B - Si are formed and grow in diffusion saturation , and carbon is pushed deep into the matrix. Linear , parabolic and logarithmic laws of motion of the interface boundary between the intermetallic layers and steel matrix was considered and solved the problem of the diffusion redistribution of carbon in the transition zone. Found that in all these cases is due to pushing of carbon its concentration are increased at the interphase boundary . In case: a) the linear moving of the interphase boundary carbon concentration at the interphase boundary is proportional to the thickness of protective coatings; b) the parabolic moving of the interphase boundary carbon concentration at the boundary remains constant; c) the logarithmic moving of the interphase boundary carbon concentration at the interphase boundary decreases with time.

 Reference

[1] G.B. Samsonov, V.P. Gluhov, Zashhitnye pokrytija na metallah (Naukova Dumka, Kiev, 1970).
[2] N. G. Kajdash, L.N. Chetverikova, Vіsnik Cherkas'kogo nacіonal'nogo unіversitetu 114, 89 (2007).
[3] O.І. Nesterenko, FHTT 5(1), 61 (2004).
[4] A.I. Nesterenko, Ukr. J. Phys. 49, 582 ( 2004).
[5] A.I. Nesterenko, Ukr. J. Phys. 49, 672 (2004).
[6] A.I. Rajchenko, Matematicheskaja teorija diffuzii v prilozhenijah (Naukova Dumka, Kiev, 1981).
[7] A.I. Nesterenko and N.G. Nesterenko Zh. Vychisl. Mat. Mat. Fiz. 24, 374 (1984).
[8] S.I. Kulikov, A.I. Nesterenko, N.G. Nesterenko, Comput. Maths Math. Phys., 33(3), 365 (1993).